Extracurricular laboratory:new discovery of (1,1′-Bis(diisopropylphosphino)ferrocene)dichloropalladium

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 215788-65-1, help many people in the next few years.COA of Formula: C22H36Cl2FeP2Pd

In heterogeneous catalysis, the catalyst is in a different phase from the reactants. COA of Formula: C22H36Cl2FeP2Pd, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 215788-65-1, name is (1,1′-Bis(diisopropylphosphino)ferrocene)dichloropalladium. In an article,Which mentioned a new discovery about 215788-65-1

Palladium(II) complexes with the formula [Pd(H2O)(OTs)(P-P)]OTs, where P-P is 1,1?-bis-(dimethylphosphino)ferrocene (dmpf), 1,1?-bis(diethylphosphino)ferrocene (depf), or 1.1?-bis- (diisopropylphosphino)ferrocene (dippf), have been synthesized and used to catalyze the carbonylation of ethylene in MeOH, water, or a 1/1 water/1,4-dioxane mixture. In MeOH, the reactions catalyzed by the dmpf and depf complexes gave alternating polyketone (alt-E-CO), while methyl propanoate and 3-pentanone were selectively produced with the dippf catalyst. The last catalyst was inactive in aqueous solvent. In contrast, the dmpf and depf catalysts were active in either water or water/1,4-dioxane for the copolymerization of CO with ethylene. These two catalysts were efficient also for the terpolymerization of CO with ethylene and propene in MeOH or water/1,4-dioxane. Operando high-pressure NMR experiments and in situ reactions with model compounds have provided useful information to rationalize the activity and selectivity of the catalytic systems investigated.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 215788-65-1, help many people in the next few years.COA of Formula: C22H36Cl2FeP2Pd

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method