Electric Literature of 14220-64-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd. In a Article£¬once mentioned of 14220-64-5
Synthesis and catalytic activity of ruthenium(II) complexes containing pyridine-based tridentate triamines (? NNN ?) and pyridine carboxylate ligands (NO )
The reaction of [(p-cymene)RuCl2]2 with K[NO a-b] (NO- = 2-picolinate, a or 2-quinaldinate, b) gave neutral [(p-cymene)RuCl(NOa-b)] (1a-b), complexes which were treated with pyridine-based meridional triamine ligands (?NNN ?) to create complexes of the type [RuCl(NOa-b) (?NNN?)] (2a: ?N = Nd, NOa- = 2-picolinato; 2b: ?N = Nd, NOb- = 2-quinaldinato; 3a: ?N = Nb, NOa- = 2-picolinato; 3b: ?N = Nb, NOb- = 2-quinaldinato; 4a: ?N = Np, NOa- = 2-picolinato; 4b: ?N = Np, NOb- = 2-quinaldinato). The new compounds were characterized by elemental analysis, IR and NMR spectroscopy and, 1b was studied by single crystal X-ray diffraction. The complexes 1-4 have been employed as catalysts for the transfer hydrogenation (TH) of acetophenone derivatives to secondary alcohols in the presence of KOH using 2-propanol as a hydrogen source at 82 C. The highest catalytic activity was obtained with 3a.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 14220-64-5
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method