Synthetic Route of 53199-31-8, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 53199-31-8, Name is Bis(tri-tert-butylphosphine)palladium, molecular formula is C24H54P2Pd. In a Article£¬once mentioned of 53199-31-8
Palladium-Catalyzed Cycloisomerization of 1,6-Enynes Using Alkyl Iodides as Hydride Source: a Combined Experimental and Computational Study
A palladium-catalyzed cycloisomerization of 1,6-enynes using alkyl iodides as hydride sources has been developed. The method turns undesired beta-hydride elimination of alkyl iodides into a strategic advantage, efficiently giving rise to dihydropyridin-2(1H)-ones and tetrahydropyridines containing exocyclic double bonds with excellent chemo- and regio-selectivity. Experimental and computational studies support a reaction mechanism involving hydride transfer via beta-hydride elimination/palladium(II) hydride migratory insertion. (Figure presented.).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 53199-31-8. In my other articles, you can also check out more blogs about 53199-31-8
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method