Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Computed Properties of C51H42O3Pd2. Introducing a new discovery about 52409-22-0, Name is Pd2(DBA)3
Self-assembly of three-dimensional (3-D) architecture using terpyridine (tpy)-based building blocks is challenging and seldom addressed due the fixed geometry (around 180) of tpy-M(ii)-tpy (M = Ru, Fe, Zn, and Cd) connectivity. Here we describe the self-assembly of 3-D giant metallo-supramolecular cubes using three-armed terpyridine ligands constructed on adamantane with molecular weight up to 18 k and edge length at ?4.9 nm, which is significantly larger than the sizes of previous metallo-supramolecular cubes. Instead of using metal center as vertices in the commonly used synthetic strategy of 3-D molecular coordination ensembles, these cages [M 12L8] bear 8 ligands as vertices with 12 metal ions on the edges. With a suitable edge length, the giant cubes appear to be the sole product after self-assembly from a variety of possible architectures. The 3-D metallo-supramolecules were characterized and supported by NMR, DOSY, ESI-MS, travelling wave ion mobility-MS and AFM. The Royal Society of Chemistry 2014.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C51H42O3Pd2, you can also check out more blogs about52409-22-0
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method