Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: 32005-36-0, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 32005-36-0
The reaction of Pd(dba)2 (dba = dibenzylideneacetone) with [W3Se4(H2O)9]4+ in 2 M HCI gives the cuboidal cluster [W3(PdCI)Se4(H 2O)9]3+, which undergoes edge-to-edge condensation and crystallizes from Hpts solutions as edge-linked double-cubane cluster [{W3PdSe4(H2O)9} 2](pts)8 · 18H2O (pts- = p-toluenesulfonate). The substitution of Cl-by different ligands, including phenylsulfinate PhSO2-, was explored. The phenylsulfinate complex was crystallized as a 2:1 adduct with cucurbit[6]uril (C36H36N24O12), [W 3(Pd(PhSO2)Se4(H2O) 8.58Cl0.42]2(C36H 36N24O12)Cl5.16 · 16.83H 2O, and its structure was determined by X-ray diffraction. Solution studies indicate that the Pd atom is able to stabilize the pyramidal tautomer of hypophosphorous and phosphorous acid: HP(OH)2 and P(OH)3. Kinetic studies were carried out on the reactions with H3PO 2 and thiocyanate, which were found to proceed in two and three kinetically resolvable steps, respectively. The kinetic results are discussed in terms of the mechanistic proposals put forward in the literature for related complexes. To gain insight into the details of the substitution kinetics in these kinds of clusters, the reaction of the related [W3S 4(H2O)9]4+ complex with NCS – has been reexamined, and the results obtained provide for the first time information about the rates of substitution of the whole set of nine-coordinated water molecules.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method