Final Thoughts on Chemistry for Bis(benzonitrile)palladium chloride

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, SDS of cas: 14220-64-5, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd

By introducing 2,6-bis(2-benzimidazolyl)pyridyl and 2,6-di-(pyrazol-3-yl)pyridine derivatives as ligand in the reaction system, three new transition-metal coordination complexes have been successfully synthesized, namely, [Co(HL1)2] (1), [Ni(HL1)2] (2), and [Ni3(H2L2)2(HL2)2](OH)3(Ac)H2O (3) (H2L1=2,6-bis(benzimidazol-2-yl)pyridine and H2L2=2,6-di-(5-phenyl-1H-pyrazol-3-yl)pyridine). They are all characterized by elemental analysis, IR spectroscopy, UV absorption spectroscopy, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. Structural analysis shows that the structures of complexes1 and 2 are similar. They are constructed from one metal (Co, Ni) atom and two 2,6-bis(benzimidazol-2-yl)pyridine ligands (HL1-); the HL1- ligand is in the tridentate coordination mode with N3 donors. Complex3 is a trinuclear Ni complex with four 2,6-di-(5-phenyl-1H-pyrazol-3-yl)pyridine (H2L2) ligands, in which the H2L2 possesses two coordination fashions: terminal tridentate and bridging tetradentate. In addition, the surface photovoltage spectroscopy and photocatalytic activities of complexes1-3 were investigated in detail. The results reveal that complex3 possesses higher photocatalytic activity. A coordinated approach: The coordination complexes [Co(HL1)2], [Ni(HL1)2], and [Ni3(H2L2)2(HL2)2](OH)3(Ac)H2O (H2L1=2,6-bis(benzimidazol-2-yl)pyridine, H2L2=2,6-di-(5-phenyl-1H-pyrazol-3-yl)pyridine) have been synthesized and characterized systematically. Surface photovoltage spectroscopy indicates p-type semiconductor characteristics and the ability to act as a photocatalyst to degrade the dye methylene blue (MB; see figure).

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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method