In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 21797-13-7, name is Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, introducing its new discovery. Recommanded Product: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate
Pinpoint-fluorinated phenanthrene synthesis based on C-F bond activation of difluoroalkenes Dedicated to Prof. Veronique Gouverneur on the occasion of her receipt of the 2014 ACS Award for Creative Work in Fluorine Chemistry.
Treatment with a cationic palladium(II) catalyst promoted the Friedel-Crafts-type cyclization of 1,1-difluoro-1-alkenes bearing a biphenyl skeleton to afford regioselectively fluorinated (pinpoint-fluorinated) phenanthrenes via C-F bond activation. The obtained pinpoint-fluorinated phenanthrenes were observed to be organized by pi-pi and C-H?F interactions to exhibit columnar and layer structures in the solid state.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method