The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about The versatility of molecular ruthenium catalyst RuCl(COD)(C5Me5), the main research direction is review ruthenium cyclooctadienyl pentamethylcyclopentadiene catalyst organic synthesis; alkyne cross coupling allyl alc ruthenium catalyst review; dimerization alkyne ruthenium catalyst review; bicyclohexane preparation ruthenium catalyst review.Formula: C18H28ClRu.
This review reports the contribution of the catalyst precursor RuCl(COD)C5Me5 to the selective transformation of alkynes to generate high value chems. with atom economy reactions. Ruthenium activation processes are discussed. Successively presented are (i) the oxidative cross-coupling of alkyne and allyl alc. to generate γ,δ-unsaturated aldehydes, (ii) the head-to-head dimerization of alkynes in the presence of carboxylic acids, via a mixed Fischer-Schrock type biscarbene-ruthenium complex, to give functional dienes, and that of propargyl alcs., via cyclobutadienyl-ruthenium intermediate, to produce cyclobutene derivatives, (iii) the addition of diazoalkanes to alkynes leading to functional dienes via double carbene addition and (iv) the reaction of diazoalkanes to enynes leading to new bicyclo[3.1.0]hexane compounds Most of the above catalytic reactions involve carbene-ruthenium catalytic species of type Cp(CL)Ru(biscarbene) or Cp(Cl)Ru:CHR.
Although many compounds look similar to this compound(92390-26-6)Formula: C18H28ClRu, numerous studies have shown that this compound(SMILES:[Cl-][Ru+2]1234567(C8(C)=C4(C)[C-]5(C)C6(C)=C87C)[CH]9=[CH]1CC[CH]2=[CH]3CC9), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method