Application of 14220-64-5, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 14220-64-5, Bis(benzonitrile)palladium chloride, introducing its new discovery.
fac-[ReBr(CO)3(L1,2)] L1 = 1-ethyl-2-(pyridin-2-yl)benzimidazole (1) and L2 = 1-[(pyridin-2-yl) benzimidazole]-propyl-sulfonic acid (2), fac-[Re2Br2(CO)6L3] (3) L3 = 1,1?-(hexane-1,6-diyl)bis[2-(pyridin-2-yl)1H-benzimidazole] and fac-[ReBr(CO)3(L4,5-kappa2N1N2)] (L4 = 2,6-bis(benzimidazol-2?-yl)pyridine (4) and L5 = 2,6-bis(1-ethyl-benzimidazol-2?-yl)pyridine (5) were synthesized and fully characterized using different spectrocopic and analytical tools. The spectrocopic data showed coordination of L1-3 to fac-ReBr(CO)3via the benzimidazole and pyridine N-atoms. For 4 and 5, the absence of a two-fold axis of symmetry for L4,5 in the 1H NMR spectra reflect the kappa2N1,N2 mode of coordination. The electronic properties of 1-5 were investigated by time-dependent density functional theory calculations in the singlet and triplet states. The ligands and their Re(i) complexes were assessed for their potential antimicrobial activity. Compound 5 was screened against non-malignant cell line (noncancerous human embryonic kidney cell line (HEK293)) as well as evaluated for its blood compatibility.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application of 14220-64-5. In my other articles, you can also check out more blogs about 14220-64-5
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method