Never Underestimate the Influence Of 78-50-2

From this literature《Solvent-Controlled Intermolecular Proton-Transfer Follows an Irreversible Eigen-Weller Model from fs to ns》,we know some information about this compound(78-50-2)Name: Tri-n-octylphosphine Oxide, but this is not all information, there are many literatures related to this compound(78-50-2).

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Solvent-Controlled Intermolecular Proton-Transfer Follows an Irreversible Eigen-Weller Model from fs to ns, published in 2021-12-31, which mentions a compound: 78-50-2, mainly applied to solvent controlled intermol proton transfer, Name: Tri-n-octylphosphine Oxide.

Intermol. Proton Transfer (PT) dynamics can be best studied by optical spectroscopy, which can cover the vast timescale spanned by the process. PT in a hydrogen bonding complex between a pyranine-based photoacid and a trialkyl-phosphine oxide is addressed. The photoreaction is traced with the help of femtosecond transient absorption and picosecond-resolved fluorescence. Characteristic kinetics and spectra of the intervening species are isolated by global anal. and spectral decomposition of time-resolved fluorescence. It is found that the shared proton shifts towards the phosphine site upon photoexcitation in acetonitrile. The process occurs on the sub-picosecond timescale, essentially, under solvent control. Despite the ultrafast rate, an equilibrium between the complex and the hydrogen-bonded ion pair (HBIP) is established. Further reaction steps are delayed to the nanosecond timescale, where formation of the excited deprotonated form is observed The far-reaching consistency between the various methods supports an irreversible Eigen-Weller mechanism in the excited state.

From this literature《Solvent-Controlled Intermolecular Proton-Transfer Follows an Irreversible Eigen-Weller Model from fs to ns》,we know some information about this compound(78-50-2)Name: Tri-n-octylphosphine Oxide, but this is not all information, there are many literatures related to this compound(78-50-2).

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method