New explortion of 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

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Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. category: catalyst-palladium. Introducing a new discovery about 95464-05-4, Name is 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

57 Fe Moessbauer spectroscopic data for a series of 1,1′-bis(diphenylphosphino)ferrocene metal complexes (X= halide or CO, n=2 or 4) are reported.An approximately linear correlation was found between the isomer shift (delta) and the quadruple splitting (Delta).Moreover, complexes of like co-ordination geometry fell within exclusive domains on a plot of delta vs. Delta.The results of an analysis of available crystal-structure data are consistent with these observations.The Moessbauer hyperfine interaction are discussed in relation to the geometry of the co-ordinated metal.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method