New explortion of Bis(dibenzylideneacetone)palladium

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In heterogeneous catalysis, the catalyst is in a different phase from the reactants. name: Bis(dibenzylideneacetone)palladium, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 32005-36-0, name is Bis(dibenzylideneacetone)palladium. In an article,Which mentioned a new discovery about 32005-36-0

Reaction of Diazonium Salts with Transition Metals. Part 11. Palladium-catalyzed Aryldesilylation of Alkenylsilanes by Arenediazonium Salts

Under palladium(0) catalysis, both (E)- and (Z)-RCH=CHSiMe3(R=Rh, 4-MeC6H4, 4-NO2C6H4, n-C6H13, and MeOCH2) were easily aryldesilylated by ArN2X(Ar=Ph, 4-MeC6H4, 4-BrC6H4 and 4-NO2C6H4; X=BF4, PF6, and Cl) to give (E)-RCH=CHAr and RC(Ar)=CH2 as the main products at 25 deg C in acetonitrile. anti- and syn-1,2-Elimination of Pd(0) and Me3Si from the adducts, threo- and erythro-RCH(PdX)CHSiMe3, generated from ArPdX and (E) and (Z)-RCH=CHSiMe3, respectively, are proposed for the formation of (E)-RCH=CHAr from either isomer of RCH=CHSiMe3.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 32005-36-0, help many people in the next few years.name: Bis(dibenzylideneacetone)palladium

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method