New explortion of Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Product Details of 21797-13-7, you can also check out more blogs about21797-13-7

Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Product Details of 21797-13-7. Introducing a new discovery about 21797-13-7, Name is Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Mediated Electrochemical Reduction of CO2. Preparation and Comparison of an Isoelectronic Series of Complexes

The preparation and characterization of complexes of the type(BF4)2 are described (for M = Ni, L is P(OMe)3 and PEt3; for M = Pd, L is CH3CN, P(OMe)3, PEt3, P(CH2OH)3, and PPh3; for M = Pt, L is PEt3; triphos is PhP(CH2CH2PPh2.On the basis of cyclic voltammetry and bulk electrolysis expariments; the Pd complexes are shown to catalyze the electrochemical reduction of CO2 to CO in acidic acetonitrile solutions.The analogous Ni and Pt complexes are not catalysts for CO2 reduction under the same conditions.Kinetic studies have been carried out on (BF4)2 and a mechanism for the reduction of CO2 is proposed.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Product Details of 21797-13-7, you can also check out more blogs about21797-13-7

Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method