52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, belongs to catalyst-palladium compound, is a common compound. Recommanded Product: 52522-40-4In an article, once mentioned the new application about 52522-40-4.
Nitrile-functionalized NCN-pincer complexes of type [MBr(N{triple bond, long}C-4-C6H2(CH2NMe2)2-2,6)] (6a, M = Pd; 6b, M = Pt) (NCN = [C6H2(CH2NMe2)2-2,6]-) are accessible by the reaction of Br-1-N{triple bond, long}C-4-C6H2(CH2NMe2)2-2,6 (2b) with [Pd2(dba)3 · CHCl3] (5a) (dba = dibenzylidene acetone) and [Pt(tol-4)2(SEt2)]2 (5b) (tol = tolyl), respectively. Complex 6b could successfully be converted to the linear coordination polymer {[Pt(N{triple bond, long}C-4-C6H2(CH2NMe2)2-2,6)](ClO4)}n (8) upon its reaction with the organometallic heterobimetallic pi-tweezer compound {[Ti](mu-sigma,pi-C{triple bond, long}CSiMe3)2}AgOClO3 (7) ([Ti] = (eta5-C5H4SiMe3)2Ti). The structures of 6a (M = Pd) and 6b (M = Pt) in the solid state are reported. In both complexes the d8-configurated transition metal ions palladium(II) and platinum(II) possess a somewhat distorted square-planar coordination sphere. Coordination number 4 at the group-10 metal atoms M is reached by the coordination of two ortho-substituents Me2NCH2, the NCN ipso-carbon atom and the bromide ligand. The N{triple bond, long}C group is para-positioned with respect to M.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 52522-40-4
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method