52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, belongs to catalyst-palladium compound, is a common compound. Safety of Tris(dibenzylideneacetone)dipalladium-chloroformIn an article, once mentioned the new application about 52522-40-4.
Gorlos-phos: Addressing the stereoselectivity in palladium-catalyzed exo-mode cyclization of allenes with a nucleophilic functionality
A novel catalyst system has been indentified for addressing the long-standing issue of Z/E stereoselectivity in palladium-catalyzed exo-mode cyclization reactions of allenes bearing a nucleophilic functionality with organic halides or their equivalents. The readily accessible, sterically hindered monophosphine ligand Gorlos-Phos¡¤HBF4 imparts a remarkable stereocontrolling ability with broad generality under Pd catalysis.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method