In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Application In Synthesis of Pd2(DBA)3, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 52409-22-0, name is Pd2(DBA)3. In an article,Which mentioned a new discovery about 52409-22-0
Expedient Pd-Catalyzed alpha-Arylation towards Dibenzoxepinones: Pivotal Manske’s Ketone for the Formal Synthesis of Cularine Alkaloids
The general synthesis of diversely substituted dibenzoxepinones by a combined Pd-catalyzed alpha-arylation and SNAr strategy is reported and applied to the synthesis of Manske’s ketone, a key intermediate en route to the total synthesis of cularine alkaloids. In the course of this work, an unanticipated ring contraction reaction to a xanthone was observed and serves as a caveat for the conditions of the widely used alpha-arylation reaction.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method