One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Computed Properties of C52H43Cl3O3Pd2, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, molecular formula is C52H43Cl3O3Pd2
Biferrocene NCN pincer metal-d8 complexes: Synthesis, reaction chemistry and cyclovoltammetric studies
The synthesis of biferrocene-bridged NCN pincer palladium and platinum complexes (NCN = [1-C6H2(CH2NMe2)2 -3,5]-) is discussed. Sonogashira cross-coupling of [(eta5-C5H4)Fe(eta5-C 5H4C{triple bond, long}CH)]2 (1) with I-1-NCN-4-X (2a, X = H; 2b, X = Br) produces [(eta5-C5H4)Fe(eta5-C 5H4C{triple bond, long}C-1-NCN-4-X)]2 (3a, X = H; 3b, X = Br). Homobimetallic 3b further reacts with [Pd2(dba)3 ¡¤ CHCl3] (4) or [Pt(tol)2(SEt2)]2 (5) (dba = dibenzylidene acetone, tol = 4-tolyl), respectively, to give tetrametallic [(eta5-C5H4)Fe(eta5-C 5H4C{triple bond, long}C-4-NCN-1-MBr)]2 (6, M = Pd; 7, M = Pt) in which NCN-MBr fragments are connected by a biferrocene unit. Cyclovoltammetric studies show that the ferrocene moieties can independently be oxidized. The difference of the Fe(II)/Fe(III) redox couples amounts to ca. 300 mV and is not affected by the nature of the NCN pincer metal moities.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method