32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Quality Control of Bis(dibenzylideneacetone)palladiumIn an article, once mentioned the new application about 32005-36-0.
Chiral N,N-chelates of formula 6-Me-pyridine-2-CH=N-R (1) and R-N=CH- CH=N-R (2) (R = 6-deoxy-alpha-D-glucoside or 6-deoxy-alpha-D-mannoside residue) and their palladium(0) complexes [Pd(N,N-chelate)(olefin)] (I) were prepared. Symmetrical type 2 ligands induced higher enantioselectivity in the coordination of prochiral olefins. The ability of a type 1 chelate to promote a stereoselective process was also assessed, i.e. dimethylfumarate inserted into the Pd-Me bond formed upon methylation of a type I complex with 50% ee. Finally, a water-soluble Pd0 complex was also prepared by deprotecting the alcoholic functions on the sugar residue, and its molecular structure- determined through X-ray diffractometry.
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method