14220-64-5, Name is Bis(benzonitrile)palladium chloride, belongs to catalyst-palladium compound, is a common compound. Recommanded Product: Bis(benzonitrile)palladium chlorideIn an article, once mentioned the new application about 14220-64-5.
Polymer supported and unsupported oxovanadium(IV) complexes with 2,6-bis(benzimidazolyl)pyridine were synthesized and characterized by elemental analyses, molar conductance, magnetic moment measurements, electronic, IR, ESR spectral studies, LC?MS and thermogravimetric analysis. Based on the results, an octahedral geometry was intended around V(IV) complexes. Polymer-anchored V(IV) complex catalyzed the oxidation of benzyl alcohols in acetonitrile with O2 as an oxidant. Several parameters were differed to optimize the reaction conditions. Under the optimized reaction conditions, benzyl alcohol oxidation confirmed 96% conversion with 100% selectivity towards benzaldehyde. The developed catalyst revealed excellent benzyl alcohol oxidation at moderate temperature in presence of oxygen making the reaction simpler and environmentally benign. The polymer anchored V(IV) complex showed excellent recyclability as compared to its unsupported analogue. Graphical Abstract: [Figure not available: see fulltext.].
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Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method