The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 14871-92-2 is helpful to your research. Electric Literature of 14871-92-2
Electric Literature of 14871-92-2, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 14871-92-2, molcular formula is C10H8Cl2N2Pd, introducing its new discovery.
Cyclometallation Reactions of 6-(2-Thienyl)-2,2′-bipyridine with d8 Transition Metal Ions
The potentially terdentate ligand 6-(2-thienyl)-2,2′-bipyridine (Hthbipy) reacts with 2- (M = Pd or Pt) under mild conditions to give cyclometallated complexes in which the thienyl ring is metallated at the 3 position.The metallated complexes (M = Pd or Pt) react with trimethyl phosphite to give phosphonate complexes > and with Na (Hacac = acetylacetone) to give with a C-bonded acac ligand.Under mild conditions, the non-metallated compound can be isolated.In contrast, the reaction ofHthbipy with Na at ambient temperature yields the non-metallated complex , but upon heating this, or performing the reaction at higher temperatures, the metallated compound is obtained.X-Ray structural analysis of this complex reveals it to be dimeric where the ligand has metallated at the 5 position of the thienyl ring and adopts a bridging N,C mode , a = 9.271(5), b = 14.214(10), c = 16.194(10) Angstroem, alpha = 108.11(5), beta = 96.55(5), gamma = 111.46(5) deg, Z = 2, R = 0.075, R’ = 0.094>.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 14871-92-2 is helpful to your research. Electric Literature of 14871-92-2
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method