Related Products of 95464-05-4, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.95464-05-4, Name is 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, molecular formula is C35H32Cl4FeP2Pd. In a Article£¬once mentioned of 95464-05-4
New acetonyl palladium(II) complexes
[Pd(CH2C(O)Me)Cl]n (1), reacts with P- and N-donor ligands to afford cis-[Pd{CH2C(O)Me}Cl(dppf)] (dppf = bis(diphenylphosphino)ferrocene (2)) and [Pd(CH2C(O)Me)ClL 2] (L = pyridine = py (3), 4-Me-pyridine = Mepy (4), 4- tBu-pyridine = tBupy (5)). Reaction of 3 or 3-5 with 1 equiv of [Tl(acac)] or TlTfO and L affords, respectively, [Pd(CH 2C(O)Me}(O,O-acac)(py)] (6) or [Pd(CH2C(O)Me)L 3]TfO (L = py (7), Mepy (8), tBupy (9)). The reaction of 9 with 1 equiv of (Ph2P(CH2)2}2PhP (triphos) gave [Pd{CH2C(O)Me}(triphos)]TfO (10). Complex 1 reacts with norbornene (nbn) followed by addition of L2 (1:2:1), with 1,5-cyclooctadiene (cod) (1:1) or with 1, 1-dimethyl aliene (dma) to give [Pd{(nbn)-CH2C(O)Me)ClL2] (L2 = 2,2?-bipyridine (bpy) (11), 4,4?-di-tert-butyl 2,2?-bipyridine (dbbpy) (12)), [Pd(CH2C(O)Me]Cl(cod)] (13), or [Pd(eta 3-CH2C(CH2C(O)Me]Cl]2 (14), respectively. The structures of complexes 3, 8, 11, and 13 have been solved by X-ray diffraction studies.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 95464-05-4
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method