Chemistry is traditionally divided into organic and inorganic chemistry. Safety of 1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 95464-05-4
Synthesis and spectroscopic properties of beta,beta?-dibenzo-3,5,8-triaryl-BODIPYs
A series of beta,beta?-bicyclo-3,5-diaryl-BODIPYs were synthesized from the corresponding beta,beta?-bicyclo-3,5-diiodo-BODIPYs (1a,b) via Pd(0)-mediated Suzuki cross-coupling reactions in 82-92% yields. Subsequent aromatization with DDQ afforded the corresponding beta,beta?-dibenzo-aryl-BODIPYs, which showed red-shifted absorptions and emissions in the near-IR range. The dibenzo-appended BODIPYs showed characteristic 1H-, 13C-, 11B- and 19F-NMR shifts, and nearly planar conformations by X-ray crystallography.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method