One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Formula: C14H10Cl2N2Pd, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd
Three zinc(II) complexes presenting a ZnN6 chromophore and with peroxodisulfate as the counter-ion
The crystal structures of three Zn complexes with the peroxodisulfate anion (pds2-) acting as counter-ion are reported, namely bis(2,2?:6?,2?-terpyridine-k3N)zinc(II) hexaoxo-mu-peroxo-disulfate(VI) dihydrate N,N-dimethylformamide solvate, [Zn(C15H11N3)2](S2O 8)·2H2O·C3H7NO or [Zn(tpy)2](pds)·2H2O·DMF, (I), bis[2,4,6-tris(2-pyridyl)-1,3,-5-triazine-k2N2,N 4]zinc(II) hexaoxo-mu-peroxo-disulfate(VI) dihydrate, [Zn(C 18H12N6)2](S2O 8)·2H2O or [Zn(tpt)2](pds)·- 2H2O, (II), and bis[2,6-bis(1H-benzimidazol-2-yl-kN 3)-pyridine]zinc(II) hexaoxo-mu-peroxo-disulfate(VI) N,N-dimethylformamide trisolvate, [Zn(C19H13N 5)2](S2O8)·3C 3H7-NO or [Zn(bbp)2](pds)·3DMF, (III), where tpy is 2,2?:6?,2?-terpyridine, tpt is 2,4,6-tris(2-pyridyl)-1,3,5-triazine, bbp is 2,6-bis(1H-benzimidazol-2-yl) pyridine and DMF is N,N-dimethylformamide. The three structures are monomeric and present the Zn cation in a distorted octahedral environment, defined by two chelating tricoordinated ligands at almost right angles to each other. These cationic entities interact with an anionic network composed of hydrogen-bonded pds2- anions and solvate water and DMF molecules via Coulombic forces, and with each other through a number of pi-pi and C=C…pi contacts connecting the aromatic rings. The pds2- anions stabilize the structures in unprecedented counter-ion behaviour.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Formula: C14H10Cl2N2Pd, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 14220-64-5, in my other articles.
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method