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Water Soluble, Zero-valent, Platinum-, Palladium-, and Nickel-P(CH2OH)3 Complexes: Catalysts for the Addition of PH3 to CH2O

The phosphine P(CH2OH)3 forms water soluble complexes of the type 4> (M=Pt, Pd, or Ni) which are catalysts for the addition of PH3 to CH2O and the Pt complex is readily protonated by water; the crystal structure of the Pd complex is also described.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method