Recommanded Product: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about First Ruthenium-Catalyzed Allylation of Thiols Enables the General Synthesis of Allylic Sulfides.
Ruthenium-catalyzed allylation of both aliphatic and aromatic thiols with allylic reagents, including allyl alcs., under extremely mild conditions was found. E.g., treatment of aliphatic and aromatic thiols, represented by pentanethiol and benzenethiol, with allyl Me carbonate in the presence of 5 mol % 1,5-cyclooctadiene(pentamethylcyclopentadiene)ruthenium chloride, in MeCN at room temperature 1 h under Ar gave the corresponding allylic sulfides, 96% allyl pentyl sulfide and 91% allyl Ph sulfide.
This literature about this compound(92390-26-6)Recommanded Product: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)rutheniumhas given us a lot of inspiration, and I hope that the research on this compound(Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method