Electric Literature of 32005-36-0, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 32005-36-0, molcular formula is C34H28O2Pd, introducing its new discovery.
Synthetic and structural studies on the transition-metal fullerene complexes (eta2-C60)M[(eta5-Ph 2PC5H4)2Ru]
A toluene solution of C60 reacted with an equimolar quantity of M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (eta 5-Ph2PC5H4)2Ru or with M(PPh3)4 and (eta5Pb2PC 5H4)2Ru at room temperature to give the dinuclear transition-metal fullerene complexes (eta2-C 60)M[(eta5Ph2PC5H 4)2Ru] (1, M = Pd; 2, M = Pt), whereas the o-dichlorobenzene solution of C60 reacted with an equimolar amount of M(dba)2 and [(eta5-Ph2PC5H 4)2Co]+(PF6)- or with M(PPh3)4 and [(eta5-Ph2PC 5H4)2Co]+(PF6) – under similar conditions to afford the dinuclear transition-metal fullerene complexes (eta2-C60)M[(eta 5-Ph2PC5H4)2Co] +(PF6)- (3, M = Pd; 4, M = Pt). In addition, the related complex {[eta5-Ph2P(O)C6H 4]2Co}+(PF6)- (5) was prepared by oxidation of [(eta5-Ph2-PC5H 4)2Co]+(PF6)- with an excess amount of aqueous peracetic acid in acetone at room temperature. While 1-4 are the first examples of neutral and cationic dinuclear M/Ru and M/Co (M = Pd, Pt) fullerene complexes, 5 is the first organocobalt Cp complex containing a phosphoryl substituent. All products 1-5 have been fully characterized by elemental analysis, spectroscopy, and X-ray crystal diffraction techniques and, for 1 and 2, by cyclic voltammetry.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 32005-36-0 is helpful to your research. Electric Literature of 32005-36-0
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method