Some scientific research about Bis(dibenzylideneacetone)palladium

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Chemistry is traditionally divided into organic and inorganic chemistry. Application In Synthesis of Bis(dibenzylideneacetone)palladium, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 32005-36-0

Palladium(II) coordination and cyclometallated complexes derived from 3- and 5-aryl-substituted pyrazoles

Palladium(II) coordination complexes of nine 3- or 5-arylpyrazoles (phenyl, 2-bromophenyl, or 3-methoxyphenyl), as well as of 3,5-diphenylpyrazole, are reported.A cis-trans mixture of isomers is found in the case of 3-aryl-1-methylpyrazoles, the cis-isomers being transformed into trans by heating.Only trans isomers are isolated with the other ligands.Cyclopalladation of 3-aryl-1-methylpyrazoles can be performed with palladium(II) acetate, and the resultant mu-acetate bridged dimers can be transformed into mu-chloro bridged dimers or acetylacetonate monomers.The structures of the complexes have been characterized by 1H- and 13C-NMR spectroscopy.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method