Some scientific research about Tris(dibenzylideneacetone)dipalladium-chloroform

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52522-40-4, Name is Tris(dibenzylideneacetone)dipalladium-chloroform, belongs to catalyst-palladium compound, is a common compound. Product Details of 52522-40-4In an article, once mentioned the new application about 52522-40-4.

An asymmetric [3 + 2] cycloaddition reaction of vinyl epoxides with alpha,beta-unsaturated ketones, the single activated electron-deficient alkenes, has been achieved under Pd-catalysis in excellent diastereo- and enantioselectivity. The utilities of the protocol are demonstrated by transformation of the products into other useful chiral molecules. Density functional theory calculations rationalize the stereocontrol of the reaction.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method