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Syntheses, crystal structures, and photoluminescent properties of PdII complexes containing a disulfanenitrile ligand

The bidendate ligand Ph2S(=N( Ph2)S?N)2 (ndsdsd) was used to prepare new PdII complexes. The homoleptic complex, [Pd(ndsdsd)2]Cl2 (1) and the heteroleptic complexes, [Pd(diimine)( ndsdsd)]Cl2 (diimine: 2,2-bipyridine (2), 1,10-phenanthroline (3a), and 4,7-diphenyl-1,10-phenanthroline (3b)) were prepared, and the molecular structures of 13 were characterized. The complexes 2 and 3 are not emissive at ambient temperature in the solid state, but the homoleptic complex 1 shows an unstructured emission bond (max = 690 nm).

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method