Electric Literature of 14220-64-5, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd. In a Article,once mentioned of 14220-64-5
Four new bis(benzimidazole)pyridine (BBP)-containing compounds Zn(BBP)Cl[Au(CN)2], Mn(BBP)[Au(CN)2]2× H2O, Mn(BBP)Br2(MeOH) and Mn(BBP)Cl2(MeOH) ×MeOH have been synthesized and structurally characterized and their birefringence values (Deltan) determined. The structure of Zn(BBP)Cl[Au(CN)2] contains a hydrogen-bonded dimer of Zn(BBP)Cl[Au(CN)2] units which propagate into a 1D chain through Au-Au interactions, although the crystals are of poor optical quality. The supramolecular structure of Mn(BBP)[Au(CN)2]2· H2O forms a 1D coordination polymer through chains of Mn(BBP)[Au(CN)2]2 units, each containing one bridging Au(CN)2 and one forming a 2D sheet through Au-Au interactions. The supramolecular structures of Mn(BBP)Br2(MeOH) and Mn(BBP)Cl 2(MeOH)·MeOH are very similar, consisting of a complex hydrogen-bonded network between NH imidazole, methanol and halide groups to align BBP building blocks. In the plane of the primary crystal growth direction, the birefringence values of the three Mn-containing materials were Deltan=0.08(1), 0.538(3) and 0.69(3), respectively. The latter two birefringence values are larger than in the related 2,2?;6?2?- terpyridine systems, placing them among the most birefringent solids reported. These compounds illustrate the utility of extending the pi-system of the building block and incorporating hydrogen-bonding sites as design elements for highly birefringent materials and also illustrates the effect on the measurable birefringence of the crystal quality, growth direction and structural alignment of the anisotropic BBP building blocks.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 14220-64-5. In my other articles, you can also check out more blogs about 14220-64-5
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method