Related Products of 32005-36-0, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 32005-36-0, Bis(dibenzylideneacetone)palladium, introducing its new discovery.
The ferrocene-functionalised anilines 2,6-Pr2i-4-Fc-C6H2NH2 (3a), 2,6-Pr2i-4-Fc-C6H2N(SiMe 3)2 (3b), 2,6-Pr2i-4-Fc-C?C-C6H2NH 2 (5a) and 2,6-Pr2i-4-Fc-C?C-C6H 2N(SiMe3)2 (5b) (Fc=ferrocenyl) have been prepared by Pd-catalysed cross-coupling reactions. The crystal structure of 5b has been determined. The NSi2 plane and the aryl ring plane form a dihedral angle of 89.8 . The N atom is trigonal planar [C-N distance 1.459(4) A]. The Cp ring and the aryl ring planes, which are connected by the C?C spacer, form a dihedral angle of 85.8 . 3a and 5a have been utilised for the preparation of the novel redox-functionalised imido complexes [Mo(N-2,6-Pr2i-4-Fc-C6H2) 2Cl2(DME)] (6) and [Mo(N-2,6-Pr2i-4-Fc-C?C-C6H 2)2Cl2(DME)] (7) (DME=1,2-dimethoxyethane). Electrochemical investigations by cyclic voltammetry revealed a pronounced interaction between the respective N functional group and the ferrocenyl moiety for all six compounds, which is largest for 6. Elsevier Science Ltd.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Related Products of 32005-36-0. In my other articles, you can also check out more blogs about 32005-36-0
Reference：
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method