So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Serron, Scafford A.; Luo, Lubin; Li, Chunbang; Cucullu, Michele E.; Stevens, Edwin D.; Nolan, Steven P. researched the compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium( cas:92390-26-6 ).Category: catalyst-palladium.They published the article 《Enthalpies of Reaction of Cp’Ru(COD)Cl (Cp’ = C5H5, C5Me5; COD = Cyclooctadiene) with P(p-XC6H4)3 (X = Cl, F, H, CH3, CF3, OCH3) Ligands: Ligand Steric vs Electronic Contributions to the Enthalpy of Reaction》 about this compound( cas:92390-26-6 ) in Organometallics. Keywords: enthalpy cyclopentadienyl ruthenium cyclooctadiene reaction phosphine; phosphine tertiary reaction enthalpy cyclooctadieneruthenium cyclopentadienyl; steric electronic effect phosphine cyclooctadieneruthenium enthalpy; crystal mol structure cyclooctadieneruthenium cyclopentadienyl complex. We’ll tell you more about this compound (cas:92390-26-6).
The enthalpies of reaction of Cp’Ru(COD)Cl (Cp’ = η5-C5H5, η5-C5Me5; COD = cyclooctadiene) with a series of para-substituted monodentate tertiary phosphine ligands, leading to the formation of Cp’Ru(PR3)2Cl, have been measured by anaerobic solution calorimetry in THF at 30.0°. These reactions are rapid and quant. Structural studies have been carried out on three complexes in this series. The relative importance of phosphine steric vs electronic ligand parameters is more closely examined in terms of the presented quant. thermochem. and structural information. Comparisons with enthalpy data in this and related organometallic systems are also presented.
After consulting a lot of data, we found that this compound(92390-26-6)Category: catalyst-palladium can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method