Quality Control of PD2DBA3. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: PD2DBA3, is researched, Molecular C51H42O3Pd2, CAS is 60748-47-2, about Visible-Light-Enabled Carboxylation of Benzyl Alcohol Derivatives with CO2 Using a Palladium/Iridium Dual Catalyst. Author is Jin, Yushu; Toriumi, Naoyuki; Iwasawa, Nobuharu.
A highly efficient carboxylation of benzyl alc. derivatives with CO2 using a palladium/iridium dual catalyst under visible-light irradiation was developed. A wide range of benzyl alc. derivatives was employed to provide benzylic carboxylic acids in moderate to high yields. Mechanistic studies indicated that the oxidative addition of benzyl alc. derivatives was possibly the rate-determining-step. It was also found that a switchable site-selective carboxylation between benzylic C-O and aryl C-Cl moieties could be achieved simply by changing the palladium catalyst.
In some applications, this compound(60748-47-2)Quality Control of PD2DBA3 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method