Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60748-47-2, is researched, SMILESS is O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.O=C(/C=C/C3=CC=CC=C3)/C=C/C4=CC=CC=C4.O=C(/C=C/C5=CC=CC=C5)/C=C/C6=CC=CC=C6.[Pd].[Pd], Molecular C51H42O3Pd2Journal, Science China: Chemistry called Access to chiral homoallylic vicinal diols from carbonyl allylation of aldehydes with allyl ethers via palladium-catalyzed allylic C-H borylation, Author is Wang, Tian-Ci; Wang, Pu-Sheng; Chen, Dian-Feng; Gong, Liu-Zhu, the main research direction is homoallylic vicinal anti diol diastereoselective enantioselective preparation; aldehyde allyl ether allylic borylation palladium catalyst.Recommanded Product: 60748-47-2.
An asym. carbonyl allylation of aldehydes with allyl ethers proceeding via allylic C-H borylation enabled by palladium and chiral phosphoric acid sequential catalysis, providing facile access to homoallylic vicinal anti-diols such as I [R1 = n-heptyl, 4-O2NC6H4, BnOCH2, etc.; R2 = H, Me, cyclohexyl, etc.; R3 = Bn, PMB, TBSO(CH2)3, etc.] in high yields and with excellent stereoselectivity was described. This protocol enabled total synthesis of aigialomycin D to be finished within 7 steps.
Although many compounds look similar to this compound(60748-47-2)Recommanded Product: 60748-47-2, numerous studies have shown that this compound(SMILES:O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.O=C(/C=C/C3=CC=CC=C3)/C=C/C4=CC=CC=C4.O=C(/C=C/C5=CC=CC=C5)/C=C/C6=CC=CC=C6.[Pd].[Pd]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method