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Effects of the auxiliary ligands on the structures of diphenate complexes: From ID helical chain to 2D network

Two coordination polymers, [Cd(dpa)(L1)] (1) and [Cd(dpa)(L2)] ·CH3CH2OH3(2) (L1 = 2,6-bis(1H- benzimidazol-2yl)pyridine, L2 = 2,2?-(l,4-butanediyl) bis (1H- benzimidazole) (L2), both of which contain helical chain subunits, were synthesized by the reaction of CdII salts and diphenic acid (H 2dpa) with rigid, chelating and flexible, bridging auxiliary ligands, respectively. Compound 1 has a 1D helical chain structure, in which dpa 2- as bridging ligand is responsible for the formation of the main framework and L1 as chelating ligand grafts on one side of the helical chain. This structure is further extended into a 3D supramolecular framework through two kinds of strong hydrogen bonding interactions. Compound. 2 has a 2D structure, in which dpa2- bridges the CdII atoms into helical chains and L2 bridges the left- and right-handed chains into a racemic layer with, a [4,4] topology.

We’ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 14220-64-5, and how the biochemistry of the body works.Related Products of 14220-64-5

Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method