The important role of 21797-13-7

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, SDS of cas: 21797-13-7, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 21797-13-7, Name is Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, molecular formula is C8H12B2F8N4Pd

Allyl boronates are very important reagents in advanced organic synthesis for the allylation of carbonyl compounds[1] and in cross-coupling[2] reactions. A practically unrivalled property of allylboronates is their highly regio- and stereoselective addition to carbonyl compounds to afford homoallylic alcohols.[1a-d, 3] This high selectivity is mainly based on two factors: 1) Allylboronates are configurationally stable, and unlike many allyl metal compounds[4] (such as allyl- Grignard reagents, allyl lithium compounds or allylboranes) do not undergo metallotropic rearrangement and E/Z isomerization at ambient conditions. 2) The six-membered ring transition state (TS) of the allylboration of carbonyl compounds is highly conformationally constrained, which leads to a strong differentiation in the stereoselection process.[3a, 5] Method development for broadening the number of accessible functionalized allyl boronates is one of the most important challenges in organoboron chemistry.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method