In heterogeneous catalysis, the catalyst is in a different phase from the reactants. SDS of cas: 53199-31-8, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 53199-31-8, name is Bis(tri-tert-butylphosphine)palladium. In an article,Which mentioned a new discovery about 53199-31-8
We describe herein the first synthesis of silyl-and disilanyl-BODIPYs through transition-metal-catalyzed dehalosilylation of iodo-BODIPYs using a Pd(P(tBu)3)2/Et3N/toluene system. Various mono- and bis-silyl-BODIPYs, mono- and bisdisilanyl-BODIPYs and bis-BODIPYs linked by silylene and SiOSi groups were synthesized by using this straightforward method. Silyl-and disilanyl-substitution significantly modifies the spectroscopic properties of the BODIPY, in which the fluorescence quantum yields of the silyl-BODIPYs are remarkably increased, whereas the emission spectra of disilanyl-BODIPYs are red-shifted due to effective sigma(SiSi)-pi(BODIPY) conjugation.
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method