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Organometallic pi-tweezers, NCN pincers, and ferrocenes as molecular “Tinkertoys” in the synthesis of multiheterometallic transition-metal complexes
This review describes the synthesis, reaction chemistry, structures, and bonding of early-late heterodi-, heterotri-, and heterotetrametallic transition-metal complexes by applying the molecular “Tinkertoy” approach. As connecting units between the different metal atoms, pi-conjugated carbon-rich organic and/or inorganic groups can be used. The electrochemical behavior of such one-dimensional molecular wire molecules, coordination polymers, starlike structures, and dendritic oriented transition-metal species, respectively, is presented as well.
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Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method