Recommanded Product: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about Diastereoselective ruthenium-catalyzed [2+2]-cycloadditions between bicyclic alkenes and a chiral propargylic alcohol and its derivatives. Author is Villeneuve, Karine; Jordan, Robert W.; Tam, William.
Diastereoselective ruthenium-catalyzed [2+2]-cycloadditions of sym. bicyclic alkenes and a chiral propargylic alc., or its derivatives, were investigated. The cycloadditions were found to be highly chemo- and stereoselective giving anti-exo-cycloadducts, e.g., I, in moderate to good yields. Diastereoselectivities of 58:42 to 84:16 were observed with chiral propargylic alc. and its derivatives
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method