Recommanded Product: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about Ruthenium(II)-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Tricarbonyl Compounds. Author is Yamamoto, Yoshihiko; Takagishi, Hideyuki; Itoh, Kenji.
In the presence of catalytic amounts of Cp*Ru(cod)Cl, unsym. 1,6-diynes possessing a variety of functional groups reacted with electron-deficient tricarbonyl compounds at the ketone C:O double bonds to selectively afford dienones via electrocyclic ring opening of the expected α-pyrans. The intramol. Michael addition of the cycloadducts having an acetyl and an alkylidenemalonate moiety gave bicyclo[3.3.0]octenone derivatives
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method