Safety of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, is researched, Molecular C18H28ClRu, CAS is 92390-26-6, about Ruthenium-Catalyzed Cycloaddition of 1,6-Diynes with Isothiocyanates and Carbon Disulfide: First Transition-Metal Catalyzed [2 + 2 + 2] Cocyclotrimerization Involving C:S Double Bond. Author is Yamamoto, Yoshihiko; Takagishi, Hideyuki; Itoh, Kenji.
In the presence of 10 mol % Cp*Ru(cod)Cl, 1,6-diynes with a tertiary center at 4-position reacted with various isothiocyanates at their C:S double bond to afford bicyclic (2H)-thiopyranimines in 35-88% yields. The (2H)-thiopyran structure was unequivocally determined by X-ray anal. The cycloaddition of carbon disulfide with a diyne similarly gave the expected bicyclic dithiopyrone in 50% yield.
In addition to the literature in the link below, there is a lot of literature about this compound(Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium)Safety of Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium, illustrating the importance and wide applicability of this compound(92390-26-6).
Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method